The Champions League is back for Matchday 5 of the 2025-26 season.
And there are some great games on the schedule, including Chelsea vs Barcelona and Arsenal vs Bayern Munich – which we will be previewing in full.
But first, here are four more of our Champions League picks for this week, all based on the latest football betting odds from our website and app.
And to help you get the most out of your European combo bets, our Acca Boost feature increases your potential winnings by up to 50%!
*All odds are subject to change
Marseille vs Newcastle: Anytime goalscorer – Pierre-Emerick Aubameyang @ 3.00
Ex-Arsenal striker Aubameyang enters this fixture in fine form, having scored two goals and assisted two more in Marseille’s previous two Ligue 1 matches. The Gabonese forward has forged a lethal partnership with Mason Greenwood, and also netted in Marseille’s first Champions League home match of the campaign – the 4-0 win over Ajax. With Newcastle conceding eight goals in their last three away contests, we are backing Aubameyang to light up the Velodrome once again.
Liverpool vs PSV Eindhoven: Draw @ 5.90
Liverpool are in a full-blown crisis following last weekend’s 3-0 defeat to Nottingham Forest. Arne Slot’s side have lost six of the last seven in the Premier League, though have performed better in the Champions League, recording back-to-back wins over Eintracht Frankfurt (1-5) and Real Madrid (1-0). However, PSV are no mugs and enter this fixture on the back of three consecutive away league victories. The Eredivisie leaders, who are averaging close to four goals per game in the division, also beat Napoli 6-2 in Eindhoven on Matchday 3, so we fancy them to spring a surprise at Anfield by grabbing a point.
Paris Saint-Germain vs Tottenham: Anytime goalscorer – Bradley Barcola @ 2.25
PSG are looking to bounce back from the 2-1 home loss to Bayern on Matchday 4. And out-of-sorts Spurs could be the perfect opponent for the reigning European champions, with Thomas Frank’s side losing 4-1 at rivals Arsenal on the weekend. In contrast, PSG claimed a comfortable 3-0 win over Le Havre at the Parc des Princes, a match in which Barcola grabbed his fifth league goal of the campaign. With Desire Doue out injured and Ousmane Dembele only recently returning to training, more responsibility is on the shoulders of Barcola, but we expect the French winger to cope brilliantly.
Atletico Madrid to beat Inter Milan @ 2.24
This is shaping up to be a fascinating contest, one which we believe Atletico will just edge on home soil. Diego Simeone’s side are a force to be reckoned with at the Wanda Metropolitano, winning their last three matches at the stadium and scoring nine goals. Union Saint-Gilloise were beaten 3-1 by Atletico in Madrid on Matchday 4, while Inter only just beat Kazakh minnows Kairat Almaty by a 2-1 scoreline. Cristian Chivu’s side also arrive in the Spanish capital on the back of a 1-0 loss to local rivals AC Milan, while Atletico claimed a crucial 1-0 win at Getafe on the weekend. The numbers and form book suggest Atletico’s odds here represent fantastic value!
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